Valimai revolves around ACP Arjun Kumar (Ajith), a righteous police officer, who sets out on a mission to hunt down an outlaw biker gang named 'Satan Slaves' following their involvement in heinous crimes such as theft, murder and drug trafficking. While facing off the gang's leader (Kartikeya), Arjun's efforts go in vain when he finds out that his family is directly affected by the baddies. Arjun, whose mental balance is broken to pieces, decides to hit back at the criminals, who wronged him, with all he got. Whether Arjun was able to defeat the evils and save his family and society forms the rest of the story.
Arjun (Ajith) is a sincere cop with values. He doesn't see chain snatching as a petty case. The Vizag police commissioner has been waiting for such an officer.
When Arjun presents his theory that the series of chain snatching cases and biking gang activities are linked to a drug syndicate, the commissioner asks him to lead the mission.
He quickly zeroes in on the main person behind this gang (Kartikeya). But the chief of the gang has developed a network that is not easy to break in.
How will Arjun save the city and his family that somehow gets dragged into the case?
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